Uttar Pradesh Technical University (UPTU) 2007 B.Pharm Pharmaceutical Chemistry-II(Organic Chemistry-I) (OLD Syllabus) - Question Paper
Printed Pages : 3 PH -122(0)
PAPER ID : 5048
(Following Paper ID and Roll No. to be filled in your Answer Book)
Roll No.
L
(SEM. II) EXAMINATION, 2006-07 PHARMACEUTICAL CHEMISTRY - II (ORGANIC CHEMISTRY - I) (OLD)
Time : 3 Hours] [Total Marks : 80
Note : Answer all the questions. All questions carry equal marks.
1 Answer any four of the following :
(a) Hydrogen bonding
(b) Resonance theory
(c) Hybridization
(d) IUPAC name of
HoC
|
HoC |  |
C = CH2, CHs C Br2 C =C-CHs;
CHsCH2 CH2CO CH2CHs; CH3
CH2-CH CH2 CH2OH,
I
Cl CH3
ch3 - ch2 - ch2 ch2 ch = ch- ch2 cooh
CHO
structure of 4-Amimo - 2, 6-dinitro toluene cyclo hexane carbamide, Ethyl cyclohexane carboxylate, 3-Methy / hept - zyne.
2 Write on any two of the following :
(a) Structural isomerism
(b) R & S configuration
(c) Optical isomerism.
3 Answer any two of the following : 8+8=16
(a) Discuss the free radical addition reactions of butane with mechanism.
(b) Write any four chemical reactions of alkyl halides with mechanism.
(c) Write an account of
(i) Preparation of conjucated dienes
(ii) Differentiate primary, secondary and tertiary alcohols.
4 Answer any two of the following :
(a) o, p and mata orienting groups
(b) Reactions of arenes
(c) Reactions of phenols.
5 Give a brief account on any four of the 4x4=16 following :
(a) Aldol condensation
(b) Mechanism of Schiff reaction
(c) Reactions of acylhalides
(d) Synthetic applications of organolithium compounds
(e) Difference between Maleic and fumeric acid
(1) Wolf - Kishner reduction.
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