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Bharathiar University 2001 M.Sc Physics Quantum Mechanics -II - Question Paper

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Degree


3048    [Si 8 60]

(For the candidates admitted from 109 onwards) M.Sc. DEGREE EXAMINATION NOVEMBER 2001.

. Seventh Semester

Physics

QUANTUM MECHANICS II

Time. : Three hours    Masmaa 1100 marks

SECTION A - (10 x 2 = 20 marks)

Answer ALL questions.

Choose the correct answer :


2. A suitable Hamiltonian H which takes into account the mutual interactions of the electrons as well as spin, erMt iataction is *

i-i ,2m , n i tiru

vSf-

H _ j "{j

(c)

H-'S*

r . q

bL

-I1

jLd i 1

[2m

(d)

H-t

1

[2m

+"

_

ze


-2


3.    The spectroscopic value for the Marandear distance for H-molecule is

- (a) 2.5 A9 . '(b.f-0.02 A*

* > "(c) 0.74 A0    id- 0.002 A

4.    If p* is density matrix and F is any operator then (#) fe

(a) Trace |jj


c Trace (p)

fFl

P

\


c Trace p).

(c) Trace


5. Lagrangian equation for the generalised co-ordinate ai iz,

(a) |4-| = 0

BL

d,

i i/ Ml]

3 a,. dtl 3of


(c)


= 0.


= 0

(d)

d_

'dL

' BL'

dt

da(

\ 1 /


Answer ALL questions in 1 or 2 sentences :

6.    Give the connecting relation between scattering amplitude and    cross section.

7.    What is the type of atoms for which Thomas Fermi method is suited to?

8.    Give the meaning ofself-consistent*,

1

9.    Her.* will you    spin --density matrix?

1, Define Hermiatiaa operator Nk through creation

' operator oA and annihilation operator a*.

* 3 ,    3048



1


SECTION B C5 x 4 = 20 marks)

11. (a) Show that the scattering amplitude f(, $)


bears a relation with scattering cross section

Or

(H'i In the neutron proton scattering, assuming that the range of the attractive force V to be approximately, 3 x 1CH3 cm, show that the scattering amplitude will be almost isotropic (in the centre of the mass system) for neutron energy < 10 MeV.

12.    (a) What is the Poissons equation used in

't,

Thomas-Fenni statistical model to determine the potential? What are the boundary conditions for {r)?

Or .

(b) Write a note on doublet separation,

13.    (aj What ar-s the trial wave functions assumed in

H* ion problems?

Or

(b) Give examples for covalent bonding.

3048

4


14,    (a) How does Plancks concept of black body* is connected with    or "absorption of radiations by 'atoms' constituting die walls?

Or

(b) Give any two application of density matrix,

15,    (a) If the Lagrangian V for a system where the single particle Hamiltonian is Hennitian is given by,

t 4 _    --t

I = -r* 2    wi)" u f > then what

* i *

are the natures of L?

Or

(b> If af and S{ are generalised co-ordinates, what are the respective conjugate momentas valuer;? SECTION C (5x8 = 40 marks)

18. (a) Derive expression for the scattering

amplitude for the scattering by Yukawas potential,

!

Or

(b) Obtain suitable expression for the solution for

f for the seaUeringm terms of Green's functions,

5    3048


17. (a) Explain the principles involved in central field approximation,

' . Or 1 ........

(b) Discuss the coupling schemes.    -*

IS, ' (a) la a Hydrogen like- atom, the spin orbit interaction is of the fonn

zm c r

since 2L-S *J2 -L2 -S3, choose ft representation in which J2,l? -and 8s are all well defined and calculate the spin orbit.correction. -

Or ~

(b) Give a detailed account on hybridisation.

19. (a) Discuss radiation field as. am assembly of oscillators. Obtain the selection rales. '

Or    

(b) Deduce expression for the emission rate and absorption rate.    

6    '    3048

20.    (a) Outline the properties of creation and destruction operators. Describe their commutation relations.

, ' ' Or (b) Obtain quantum equation fcr the field.

S10HON D (2 x 10 20 marks)

21.    W Obtain expression for the free panicle solutk>a    partial wave analysis. Also deduce expression for scattering amplitude.

... .    Or

(b) scribe Bom's approximation to calculate the scattering amplitude f (ff, #),

22.    (a) Obtain expression for the total energy .(symmetric <* antisymmetric) for the hychogen

molecd by Hotter London method.

Or

(b) Calculate Einstein, Coefficient of induced emission and show that it is equal. to Einstein's coefficient absorption from semiclassica! theory of radiao'.



7    3048







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